Optical basicity definition
WebFeb 1, 2024 · The concept of optical basicity (Λ) is particularly suited to binary oxides and oxidic network materials such as silicates to characterize the acid–base nature of glasses and melts and to account for the complexation of metal cations by a variety of anionic … Webbasicity is a predominant factor for both properties and structure of glasses, and it may cover exhaustively the relation among composition, structure and properties. Basicity can …
Optical basicity definition
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WebThis paper reports on different physical and optical properties of Nd 3+ -doped bismuth borate glasses. The glasses containing Nd 3+ in (25 − x)Bi 2 O 3 :20Li 2 O:20ZnO:35B 2 O 3 :xNd 2 O 3 (where x = 1, 1.5, 2 mol%) have been prepared by melt-quenching method. The amorphous nature of the glasses was confirmed by X-ray diffraction studies. WebAug 13, 2002 · The acid−base properties of germanate glasses cannot presently be compared quantitatively with those of silicate, borate, and several other glasses because the optical basicity of the parent oxide, Λ(GeO2), has not yet been unequivocally established. The usual method of measuring optical basicity, relying on probe ions such as Tl+ or …
WebFeb 13, 2024 · The concept of “basicity ” has been central to our understanding of slag chemistry for many decades. Traditionally, basicity has been connected to the level of … WebEllipsometry is an optical technique that measures changes in polarization (phase, Δ, and amplitude, Ψ) of monochromatic light reflecting from matter, and these standard ellipsometric parameters Ψ and Δ are related to the complex ratio of reflection coefficient for light polarized parallel p and perpendicular s to the plane of incidence. 2.3.3.
WebAug 1, 1993 · Optical basicity is particularly useful for oxidic network systems, such as silicate, phosphate, or borate in crystalline, vitreous, and liquid (molten) form. The … WebThe concept of optical basicities initially developed by Duffy for solid oxides was successfully transferred to low melting salts such as ionic liquids (ILs). Several ionic liquids (ILs) were doped with Mn (NTf 2) 2 ( NTf 2 = bis (trifluoromethanesulfonyl)imide) as a probe to investigate the IL anion basicity by means of UV-Vis spectroscopy.
WebOptical basicity analysis of glasses containing trivalent scandium, yttrium, gallium and indium John A Duffy Chemistry Research output: Contribution to journal › Article › peer-review 18 Citations (Scopus) Overview Cite this APA Standard Harvard Vancouver Author BIBTEX RIS Duffy, J. A. (2005).
WebJul 27, 2011 · Basicity is expressed using the Smith {alpha} parameter scale. A linear relation was found between the oxide electronegativity and the Smith {alpha} parameter, … figma hunter: the old hunters editionWebPolarisability and polarising power of rare earth ions in glass: an optical basicity assessment — The University of Aberdeen Research Portal Polarisability and polarising power of rare earth ions in glass: an optical basicity assessment John A Duffy Chemistry Research output: Contribution to journal › Article › peer-review 41 Citations (Scopus) figma icons packWebOptical basicity: a scale of acidity/basicity of solids and its application to oxidation catalysis. Elisabeth Bordes-Richard, Pierre Courtine To cite this version: Elisabeth Bordes … grizzly g0602 lathe modifications