NettetEl tiazole, o 1,3-tiazole, és un compost heterocíclic que conté sofre i nitrogen; el terme "tiazole" també es refereix a una gran família de derivats.El tiazole és un líquid de color groc pàl·lid amb una olor similar a la piridina i té per fórmula molecular C₃H₃NS. L'anell de tiazole destaca per ser un component de la vitamina tiamina (B1). NettetHOF·CH3CN, a very efficient oxygen-transfer agent made readily from fluorine and aqueous acetonitrile, was reacted with various quinoxaline derivatives to give the corresponding mono N-oxides and especially the N,N‘-dioxides in very good yields under mild conditions and short reaction times.
常用氧化剂----次氟酸-乙腈配合物_反应_Rozen_Chem - 搜狐
Nettet28. mai 2014 · HOF·CH3CN: Probably the Best Oxygen Transfer Agent Organic Chemistry Has To Offer ADVERTISEMENT Log In Register Cart ACS ACS Publications C&EN … NettetHOF·CH3CN也是一个环境友好的氧化试剂,能够有效而又低污染地将醇和甲基醚氧化为酮。 酮类化合物在相同条件下也可以经过Baeyer-Villiger氧化反应得到酯类化合物。 由于具有高亲电性的氧原子,HOF·CH3CN配 … ridekcfreedom + application
Hofen - Wikipedia
Nettet28. mai 2014 · HOF·CH 3 CN excels in oxygenation of various sulfur and selenium compounds that could not be oxygenated in the past. The selectivity of the oxidation is … NettetMembers of thieno[2,3-b]thiophenes were oxidized using the HOF·CH3CN complex, transforming the sulfur atom to the corresponding sulfonyl group in high yield and under very mild conditions. NettetAt present, HOF·CH 3 CN complex is the best oxygen transfer agent that chemistry has to offer. It is readily made by passing dilute fluorine through aqueous acetonitrile and does … ridekc twitter